[Mn(bipy)_3]·(ClO_4)_2·1.875H_2O的合成晶体结构及表征SYNTHESIS AND CRYSTAL STRUCTURE OF COMPLEX [Mn(bipy)_3]·(ClO_4)_2·1.875H_2O
郭桂全,边贺东,于青,杨晓娥,朱立刚
摘要(Abstract)：
合成了配合物[M n(b ipy)3].(C lO4)2.1.875H2O(b ipy=2,2′-联吡啶),并利用X-射线单晶衍射仪确定了其结构.该配合物属六方晶系,空间群为P 63m c.在配合物中,每个M n(Ⅱ)离子与3个2,2′-联吡啶的6个氮原子配位,形成了畸变的八面体结构.C lO4-上的O原子与吡啶环上的H原子通过氢键连接成三维网状结构.
关键词(KeyWords)： 锰(Ⅱ)配合物;2,2′-联吡啶;晶体结构;合成;表征
基金项目(Foundation): 广西科学基金资助项目(0342025);; 高等学校优秀青年教师教学科研奖励计划项目
作者(Author): 郭桂全,边贺东,于青,杨晓娥,朱立刚
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