潘成学;苏桂发;

• 1:广西师范大学化学化工学院
• 2:广西师范大学化学化工学院 广西桂林541004
• 3:广西桂林541004

摘要(Abstract)：

室温下对氯苯基重氮甲烷与(Z)-2-苯基-4-苯亚甲基-5(4H)口-恶唑酮经1,3-偶极环加成反应,以82%的产率得到环加成物,再经醇解开环、水解去保护得到顺-2-(4-氯苯基)-反-3-苯基-r-1-氨基环丙烷羧酸,产率56%。环加成产物的晶体结构及其粗产物的GC-M S测定结果表明,对氯苯基重氮甲烷与口恶唑酮的环加成反应是非对映立体专一性的。

关键词(KeyWords)： 二芳基取代环丙烷氨基酸;1,3-偶极环加成反应;晶体结构

Abstract:

Keywords:

基金项目(Foundation): 广西自然科学基金资助项目(0339033);; 广西高校百名中青年学科带头人资助计划资助项目

作者(Authors): 潘成学;苏桂发;

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